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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Hadjiarapoglou, L.; | en |
| dc.contributor.author | de Meijere, A.; | en |
| dc.contributor.author | Seitz, H.-J.; | en |
| dc.contributor.author | Klein, I.; | en |
| dc.contributor.author | Spitzner, D. | en |
| dc.date.accessioned | 2015-11-24T16:58:25Z | - |
| dc.date.available | 2015-11-24T16:58:25Z | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/10686 | - |
| dc.rights | Default Licence | - |
| dc.title | Facile Synthesis of Highly Functionalized Bicyclo[3.2.1]octanes as Building Blocks for Various Natural Products | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.secondary | http://www.sciencedirect.com/science/article/pii/S0040403900768821 | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 1994 | - |
| heal.abstract | The cascade cycloaddition of 1-alkoxycyclohexadienolates 2 onto 2-chloro-2-cyclopropylideneacetate 4 yields 2-alkoxytricyclo[3.2.1.02.7octane-2,6-diones 8 under acid catalysis. The tricyclooctanones 7 can be further elaborated, e. g. by Wittig olefination and reduction of the carbonyl group, or deprotonation at the bridgehead C-7 with subsequent alkylation, acylation or aldol reaction, before they are rearranged to the highly functionalized bicyclo[3.2.1]octane derivatives 10, 11, 13, and 17, respectively. The diones 8 can also be further manipulated, e. g. by regioselective Wittig olefination at C-2. | en |
| heal.publisher | Elsevier | en |
| heal.journalName | Tetrahedron Lett | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Hadjiarapoglou-1994-Facile synthesis of highly.pdf | 301.38 kB | Adobe PDF | View/Open Request a copy |
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