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dc.contributor.authorPanagiota, S.en
dc.contributor.authorLouloudi, M.en
dc.contributor.authorDeligiannakis, Y.en
dc.date.accessioned2015-11-24T16:57:54Z-
dc.date.available2015-11-24T16:57:54Z-
dc.identifier.issn0009-2614-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10633-
dc.rightsDefault Licence-
dc.subjectelectron-paramagnetic-resonanceen
dc.subjecthumic acidsen
dc.subjectgallic aciden
dc.subjectantioxidanten
dc.subjectsemiquinoneen
dc.subjectflavonoidsen
dc.subjectadsorptionen
dc.subjectstabilityen
dc.subjectpb(ii)en
dc.subjectsilicaen
dc.titleEPR study of phenolic radical stabilization by grafting on SiO(2)en
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.cplett.2009.02.080-
heal.identifier.secondary<Go to ISI>://000264637800016-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0009261409002656/1-s2.0-S0009261409002656-main.pdf?_tid=350410f813980383542404f32a0376c3&acdnat=1333034426_adc30a9fd1a18fd963f95ab1ed445761-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2009-
heal.abstractA hybrid [SiO(2)-GA] material has been synthesized by grafting Gallic acid (3,4,5-trihydroxybenzoic acid, GA) on SiO(2) via formation of amide bonds between amine groups on aminopropyl-silica and the carboxyl group of GA. The spatial fixation of GA prevents polymerization effects. EPR spectroscopy shows that GA radicals on [SiO2-GA] show remarkable stability, comparable to that previously observed only for radicals in biological matrices on in soil organic matter. EPR reveals a bundle-like organization of the GA molecules on [SiO2-GA] material. The relation of these factors to the enhanced radical stability is discussed. (C) 2009 Elsevier B. V. All rights reserved.en
heal.publisherElsevieren
heal.journalNameChemical Physics Lettersen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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