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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Adam, W. | en |
| dc.contributor.author | Bialas, J. | en |
| dc.contributor.author | Hadjiarapoglou, L. | en |
| dc.contributor.author | Sauter, M. | en |
| dc.date.accessioned | 2015-11-24T16:57:50Z | - |
| dc.date.available | 2015-11-24T16:57:50Z | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/10624 | - |
| dc.rights | Default Licence | - |
| dc.subject | Epoxidation / Dioxirane, dimethyl / Benzofurans, 2,3-dimethy1- / Benzofuran epoxides / Quinone methides / Methanol addition | en |
| dc.title | Epoxidation of 2,3-Dimethylbenzo[b]furans by Dimethyldioxirane | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.secondary | https://docs.google.com/file/d/0BxfLht5wJUEIMDgxYjFmMDItMWQxMy00MTA5LWEzNTktYjU4OTJiZjkxYjZi/edit?hl=en | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 1992 | - |
| heal.abstract | The synthesis of epoxides 2 by the reaction of the chloro- and methyl-substituted 2,3-dimethy1benzofurans l with dimethyl-dioxirane at low temperature is reported. These labile epoxides were spectroscopically characterized (1H and 13C NMR) at subambient temperatures. Epoxidation of benzofuran l c affords a 31:69 mixture of epoxide 2c and quinone methide 3c, the latter presumably being produced by valence isomerization of the epoxide. On Warming up above 10Β°C, the epoxides 2 suffer decomposition. Treatment of epoxide 2i with methanol yields the tautomeric mixture of adducts 4i and 4i'. | en |
| heal.publisher | VCH Verlagsgesellschaft | en |
| heal.journalName | Chem. Ber. | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Hadjiarapoglou-1992-Epoxidation of 2,3-dimenthyl.pdf | 318.16 kB | Adobe PDF | View/Open Request a copy |
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