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dc.contributor.authorAslanidou, M.en
dc.contributor.authorVaimakis, T.en
dc.contributor.authorMitsionis, A.en
dc.contributor.authorTrapalis, C.en
dc.date.accessioned2015-11-24T16:57:14Z-
dc.date.available2015-11-24T16:57:14Z-
dc.identifier.issn0272-8842-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10556-
dc.rightsDefault Licence-
dc.subjectbiphasic calcium phosphateen
dc.subjectdcpden
dc.subjecthydroxyapatiteen
dc.subjecthydrolysis-precipitationen
dc.subjectin-vitro bioactivityen
dc.subjecthydroxyapatite coatingsen
dc.subjecthistological-evaluationen
dc.subjecttricalcium phosphateen
dc.subjectboneen
dc.subjectcementen
dc.subjectbiomaterialsen
dc.subjectmechanismen
dc.subjectceramicsen
dc.subjecttransformationen
dc.titleA novel approach on the preparation of biphasic calcium phosphate bioceramics under physiological conditions. The effect of the starting materialen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.ceramint.2012.06.060-
heal.identifier.secondary<Go to ISI>://000315246300070-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0272884212005895/1-s2.0-S0272884212005895-main.pdf?_tid=3fe0d9c2-5356-11e3-a000-00000aab0f6c&acdnat=1385111745_35646c2d2a4cafa6217cbb68e0053d2e-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2013-
heal.abstractBiphasic Calcium Phosphate (BCP) bioceramics were prepared in physiological pH. Salts of Calcium and Phosphate with initial molar ratio of Ca/P=1.67, similar to Hydroxyapatite (HA) stoichiometry, were precipitated by the addition of NH4HCO3 1 M. XRD results of the as prepared materials show that high crystalline CaHPO4 center dot 2H(2)O (DCPD) was produced, resulting a decrease of the initial Ca/P ratio. However ageing of the slurry under continuous stirring for 1 and 2 days time, lead to the gradual hydrolysis of dicalcium phosphate dihydrate (DCPD) to low crystalline HA producing biphasic HA/DCPD particles. Ageing time affects also the morphology of the materials. SEM images show that the initial lath-like DCPD particles with HA during the ageing were transformed firstly into bigger particles and flake like particles afterwards. The above mentioned are in accordance to the results of TG/DTA analysis. The morphology and the phase composition of the yielding materials depend on the initial concentration of HCO3- and ageing time. Hydrolysis of NH4HCO3, affects the precipitation of both Ca2+ and PO43- on the starting material, under physiological pH and thus has to be manipulated properly in order to achieve the desirable results in a possible hard tissue evaluation of in vitro bioactivity. (C) 2012 Elsevier Ltd and Techna Group S.r.l All rights reserved.en
heal.journalNameCeramics Internationalen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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