Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/10305
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dc.contributor.authorPapamichael, E. M.en
dc.contributor.authorEvmiridis, N. P.en
dc.contributor.authorThanasoulias, N.en
dc.contributor.authorStefanou, D.en
dc.date.accessioned2015-11-24T16:55:25Z-
dc.date.available2015-11-24T16:55:25Z-
dc.identifier.issn0169-7439-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10305-
dc.rightsDefault Licence-
dc.subjectexperimental designen
dc.subjectcurve fittingen
dc.subjectdata processingen
dc.subjectcalibrationen
dc.subjectperiodateen
dc.subjectchemiluminescenceen
dc.subjectpyrogallolen
dc.titleDesign of experiments for a precise estimation of the calibration curve of periodate in its determination by flow-injection analysis and chemiluminescence detection.en
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.secondary<Go to ISI>://A1995TM79500005-
heal.identifier.secondaryhttp://ac.els-cdn.com/0169743995000291/1-s2.0-0169743995000291-main.pdf?_tid=2b676612080bc4d14d59b3ba9665f090&acdnat=1335373347_d2766b5addb7fb7874dc44ba70324a7e-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate1995-
heal.abstractA design of experiments method based on the criterion of D-optimality is presented. It is applied to the estimation procedure of the parameters of a periodate calibration curve described by a model equation of the form y = ax(2)/(bx + c root x + 1) and giving the maximum possible precision using three experimental measurements. The use of four or five experimental measurements for producing the calibration curve was not found more advantageous than that of three. Simulated data were generated, for the three optimal points, and a large number of parameter estimates were obtained under constant and/or relative errors (in y) showing a robust behaviour. The %-bias and the %-excess variance based on the simulated data were found to be non-significant.en
heal.publisherElsevieren
heal.journalNameChemometrics and Intelligent Laboratory Systemsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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