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https://olympias.lib.uoi.gr/jspui/handle/123456789/10303Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Louloudi, M. | en |
| dc.contributor.author | Deligiannakis, Y. | en |
| dc.contributor.author | Hadjiliadis, N. | en |
| dc.date.accessioned | 2015-11-24T16:55:24Z | - |
| dc.date.available | 2015-11-24T16:55:24Z | - |
| dc.identifier.issn | 0020-1669 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/10303 | - |
| dc.rights | Default Licence | - |
| dc.subject | monooxygenase model system | en |
| dc.subject | binuclear copper(ii) complexes | en |
| dc.subject | reversible dioxygen binding | en |
| dc.subject | schiff-base complexes | en |
| dc.subject | aromatic hydroxylation | en |
| dc.subject | catalytic epoxidation | en |
| dc.subject | oxidation reactions | en |
| dc.subject | olefin epoxidation | en |
| dc.subject | reactivity | en |
| dc.subject | manganese | en |
| dc.title | Design and synthesis of new biomimetic materials by sol-gel: A Cu-II(histidine)(2) complex covalently bonded on a silica matrix | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.primary | Doi 10.1021/Ic980665q | - |
| heal.identifier.secondary | <Go to ISI>://000077839100040 | - |
| heal.identifier.secondary | http://pubs.acs.org/doi/pdfplus/10.1021/ic980665q | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 1998 | - |
| heal.abstract | The synthesis of a new histidine-silane derivative, Boc-His(Boc)-CONH-(CH2)(3)Si(OEt)(3), is reported. Hydrolysis and co-condensation of this monomer with tetraethoxysilane, via the sol-gel procedure, results in a hybrid inorganic-organic material that bears histidine molecules covalently bonded on a silica matrix. 1D-ESEEM and 2D-HYSCORE studies of its Cu(II) complex show that the copper atom is coordinated by two inequivalent histidine imidazoles. The new Cu(II) material exhibits catalytic activity for DTBQ formation in the presence of dioxygen, with considerable turnover rates and yields. In addition it is highly recyclable and shows high specific surface area. | en |
| heal.publisher | American Chemical Society | en |
| heal.journalName | Inorg Chem | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Louloudi-1998-Design and synthesis.pdf | 140.85 kB | Adobe PDF | View/Open Request a copy |
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