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Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/10250
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dc.contributor.authorSkoulika, S.en
dc.contributor.authorDallas, P.en
dc.contributor.authorSiskos, M. G.en
dc.contributor.authorDeligiannakis, Y.en
dc.contributor.authorMichaelides, A.en
dc.date.accessioned2015-11-24T16:55:05Z-
dc.date.available2015-11-24T16:55:05Z-
dc.identifier.issn0897-4756-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10250-
dc.rightsDefault Licence-
dc.subjectcoordination polymeren
dc.subjecthydrothermal reactionsen
dc.subjectframeworksen
dc.subjectdecarboxylationen
dc.subjectspectroscopyen
dc.subjectderivativesen
dc.subjectcopper(ii)en
dc.subjecttransitionen
dc.subjectmoleculesen
dc.subjectchemistryen
dc.titleCrystal structure and solid-state reactivity of a Cd(II) polymeric complex with acetylenedicarboxylic aciden
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primary10.1021/cm034666e-
heal.identifier.secondary<Go to ISI>://000186886600008-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdfplus/10.1021/cm034666e-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2003-
heal.abstractThe novel one-dimensional coordination polymer [Cd(ADC)(H2O)(3)] H2O, where ADC(2-) = acetylenedicarboxylate dianion, was synthesized and characterized by single-crystal X-ray diffraction. The titled compound crystallizes in the monoclinic system, P2(1)/n, a = 6.908(1) Angstrom, b = 7.946(1) Angstrom, c = 16.390(1) Angstrom, beta = 100.21(1)degrees, V = 885.4(2) Angstrom(3), and Z = 4. The structure is made up of metal-organic chains linked by hydrogen bonds to form channels along the b axis. The carbon-carbon triple bonds are in close proximity (3.27 Angstrom) along the a axis. This induces, upon heating, polymerization with formation of conjugated polycarboxylic chains. Detailed EPR studies have been performed in order to understand the polymerization process.en
heal.publisherAmerican Chemical Societyen
heal.journalNameChemistry of Materialsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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