Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/10226
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dc.contributor.authorAslanidis, P.en
dc.contributor.authorCox, P. J.en
dc.contributor.authorKaragiannidis, P.en
dc.contributor.authorHadjikakou, S. K.en
dc.contributor.authorAntoniadis, C. D.en
dc.date.accessioned2015-11-24T16:54:57Z-
dc.date.available2015-11-24T16:54:57Z-
dc.identifier.issn1434-1948-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10226-
dc.rightsDefault Licence-
dc.subjectcopperen
dc.subjectsulfur heterocyclesen
dc.subjectphosphane ligandsen
dc.subjectcu(i) complexesen
dc.subjecttolylphosphineen
dc.subjectphotolysisen
dc.subjectbromideen
dc.titleCopper(I) halide complexes with triphenylphosphane and heterocyclic thione ligands: The crystal structures of [bis(triphenylphosphane)(benzimidazole-2-thione)copper(I) iodide], [bis(triphenylphosphane)(benzothiazole-2-thione)copper(I) iodide], and bis[mu-S-(benzimidazole-2-thione)(triphenylphosphane)copper(I) chloride]en
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.secondary<Go to ISI>://000177127500044-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2002-
heal.abstractWhile the reaction of benz-1,3-imidazole-2-thione (bzimtH(2)) or benz-1,3-thiazole-2-thione (bztztH) with copper(l) iodide in the presence of two equivalents of triphenylphosphane led to mononuclear complexes of the type [CuI(PPh3)(2)(L)], the reaction of benz-1,3-imidazole-2-thione with copper(I) chloride gave a dimeric complex [CuCl(PPh3)(bzimtH(2))](2). These three compounds were characterized by IR, UV/Vis, and H-1 NMR spectroscopy, and the crystal structures determined by single-crystal X-ray diffraction methods. Vibrational, electronic, and H-1 NMR spectroscopic data of the complexes are discussed in relation to the structures. (C) Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.en
heal.publisherWileyen
heal.journalNameEuropean Journal of Inorganic Chemistryen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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