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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Plakatouras, J. C. | en |
| dc.contributor.author | Perlepes, S. P. | en |
| dc.contributor.author | Mentzafos, D. | en |
| dc.contributor.author | Terzis, A. | en |
| dc.contributor.author | Bakas, T. | en |
| dc.contributor.author | Papaefthymiou, V. | en |
| dc.date.accessioned | 2015-11-24T16:54:52Z | - |
| dc.date.available | 2015-11-24T16:54:52Z | - |
| dc.identifier.issn | 0277-5387 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/10213 | - |
| dc.rights | Default Licence | - |
| dc.subject | high-spin cobalt(ii) | en |
| dc.subject | x-ray crystal | en |
| dc.subject | electron-paramagnetic-res | en |
| dc.subject | molecular-structure | en |
| dc.subject | esr-spectra | en |
| dc.subject | tetrachlorocobaltate(ii) | en |
| dc.subject | ligands | en |
| dc.subject | nitrate | en |
| dc.subject | copper | en |
| dc.subject | derivatives | en |
| dc.title | Coordination Chemistry of Corrosion-Inhibitors of the Benzotriazole Type - Preparation and Characterization of Cobalt(Ii) Complexes with 1-Methylbenzotriazole (Mebta) and the Crystal-Structures of [Cocl2(Mebta)2], Trans-[Co(Ncs)2(Mebta)4], Trans-[Co(Ncs)2(Meoh)2(Mebta)2] and Cis-[Co(No3)2(Mebta)2] | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.secondary | <Go to ISI>://A1992JX12800013 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0277538700802375/1-s2.0-S0277538700802375-main.pdf?_tid=e0222cd6ef4077c0968f2b693adb1cec&acdnat=1333036056_e8103727e1af09562c833cbadaebddaa | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 1992 | - |
| heal.abstract | An inorganic model approach to the corrosion inhibition of metals by benzotriazoles has been initiated. The preparation and characterization of monomeric cobalt(II) complexes of the types [CoX2(Mebta)2] (X = Cl, Br, NCS, NO3), (MebtaH)[CoCl3(Mebta)], (MebtaH)2[CoCl4], [Co(NCS)2(Mebta)4], [Co(NCS)2(MeOH)2(Mebta)2] and [Co(NO3)2 L2(Mebta)2] (L = H2O, MeOH), where Mebta = 1-methylbenzotriazole, are described. Four representative complexes have been structurally characterized by single-crystal X-ray diffraction studies; [CoCl2(Mebta)2] (1), trans-[Co(NCS)2(Mebta)4] (5), trans-[Co(NCS)2 (MeOH)2(Mebta)2] (6) and cis-[Co(NO3)2(Mebta)2] (8). Mebta acts as a monodentate ligand binding through N(3). The geometry about cobalt in 1 is tetrahedral, while complexes 5, 6 and 8 have octahedral stereochemistries. The new complexes were also characterized by elemental and thermogravimetric analyses, conductivity measurements, variable-temperature magnetochemistry and spectroscopic (IR, ligand field, low-temperature ESR) methods. The data are discussed in terms of the nature of bonding and known structures. | en |
| heal.publisher | Pergamon Press Ltd. | en |
| heal.journalName | Polyhedron | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Plakatouras-1992-Coordination Chemist.pdf | 1.59 MB | Adobe PDF | View/Open Request a copy |
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