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dc.contributor.authorTsogas, G. Z.en
dc.contributor.authorGiokas, D. L.en
dc.contributor.authorVlessidis, A. G.en
dc.date.accessioned2015-11-24T16:54:52Z-
dc.date.available2015-11-24T16:54:52Z-
dc.identifier.issn0039-9140-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10212-
dc.rightsDefault Licence-
dc.subjectalkaline earth metalsen
dc.subjectcoacervationen
dc.subjectspectrophotometryen
dc.subjectwater hardnessen
dc.subjectatomic-absorption-spectrometryen
dc.subjectorganic-compoundsen
dc.subjectnatural-watersen
dc.subjectextractionen
dc.subjectvesiclesen
dc.subjectchromiumen
dc.subjectcalciumen
dc.subjectspeciationen
dc.subjectmagnesiumen
dc.subjectsamplesen
dc.titleA fast assay of water hardness ions based on alkaline earth metal induced coacervation (HALC)en
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.talanta.2009.11.003-
heal.identifier.secondary<Go to ISI>://000275612500070-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0039914009008522/1-s2.0-S0039914009008522-main.pdf?_tid=1f50f416-356b-11e3-aaf1-00000aacb362&acdnat=1381822175_3e4bb5b733a88aac1ebb1a38cc2e2385-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2010-
heal.abstractIn this work, a rapid assay of water hardness is presented based on the formation of a coacervate phase made up of multilamellar vesicles and close bilayers produced upon the reaction of alkaline earth metals with a carboxylate anionic surfactant in the presence of a co-surfactant (methanol). The procedure exploits the light scattering abilities of the coacervate phase which can be logarithmically linked to total hardness as CaCO(3) equivalents via spectrophotometric detection at 350 nm The method, abbreviated as HALC, stemming from hardness by alkaline earth metal coacervation, is straightforwardly applicable overcoming the requirement for regulation of the experimental parameters involved in the determination procedure. In total, 28 water samples with various matrix compositions and hardness contents were analyzed with satisfactory accuracy as evidenced by comparison of the results with EDTA complexometric titration The method is free from interferences from environmentally significant metal cations and inorganic anions affording detection limits as low as 13.5 mg L(-1) CaCO(3) with the aid of a correction factor. which is determined by the non-linear absorbance properties of the solution mixture, and satisfactory reproducibility (RSD =421-8.08%). (C) 2009 Elsevier By. All rights reserveden
heal.publisherElsevieren
heal.journalNameTalantaen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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