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dc.contributor.authorAdam, W.en
dc.contributor.authorGogonas, E. P.en
dc.contributor.authorHadjiarapoglou, L. P.en
dc.date.accessioned2015-11-24T16:54:45Z-
dc.date.available2015-11-24T16:54:45Z-
dc.identifier.issn0022-3263-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10190-
dc.rightsDefault Licence-
dc.subjectalkyl sulfonesen
dc.subjectrearrangementen
dc.subjectphotochemistryen
dc.subjectindanesen
dc.titleA facile diastereoselective synthesis of functionalized 1,2,3-trisubstituted benzocyclopentenes through the cycloaddition of bis(phenylsulfonyl)iodonium ylides to cyclic alkenesen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1021/Jo035362e-
heal.identifier.secondary<Go to ISI>://000186489000063-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdfplus/10.1021/jo035362e-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2003-
heal.abstractThe thermal cycloaddition of beta-disulfonyl iodonium ylides to cyclic alkenes affords exclusively 1,2,3-trisubstituted cis(1,2)/cis(2,3)-configured benzocyclopentenes by an electrophilic attack of the ylide on the olefinic double bond. This unsual transformation provides a convenient and direct method for the diastereoselective synthesis of functionalized bicyclo[3.3.0] octanes (characteristic structural units contained in polyquinane natural products), when cyclopentenes are used as cycloalkene partner.en
heal.journalNameJournal of Organic Chemistryen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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