1. Repository of OAI
  2. ΑΠΟΘΕΤΗΡΙΟ "ΟΛΥΜΠΙΑΣ"
  3. Σχολή Θετικών Επιστημών
  4. Τμήμα Χημείας
  5. Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ
Ελληνικά   English  
Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/10143
Full metadata record
DC FieldValueLanguage
dc.contributor.authorKasselouri, S.en
dc.contributor.authorGaroufis, A.en
dc.contributor.authorKalkanis, G.en
dc.contributor.authorPerlepes, S. P.en
dc.contributor.authorHadjiliadis, N.en
dc.date.accessioned2015-11-24T16:54:18Z-
dc.date.available2015-11-24T16:54:18Z-
dc.identifier.issn0340-4285-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10143-
dc.rightsDefault Licence-
dc.subjectcopper(ii) complexesen
dc.subjectcrystal-structureen
dc.subjectamide bonden
dc.subjectcoordination chemistryen
dc.subjectthermal-propertiesen
dc.subjectpalladium(ii)en
dc.subjectspectroscopyen
dc.subjectderivativesen
dc.subjectnickel(ii)en
dc.subjectproductsen
dc.titleComplexes of Divalent Transition-Metal Chlorides with the Tetradentate Schiff-Base Ligand 1,2-Bis(2'-Pyridylmethyleneimino)Benzeneen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.secondary<Go to ISI>://A1993LZ91900021-
heal.identifier.secondaryhttp://www.springerlink.com/content/r387750j0v803205/fulltext.pdf-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate1993-
heal.abstractTransition metal(II) chloro complexes of the new Schiff base ligand 1,2-bis(2'-pyridylmethyleneimino)benzene (L), derived from 2-pyridinecarboxaldehyde and 1,2-phenylenediamine, were prepared. Compounds of [MnLCl2].H2O, [CoLCl2].2H2O, [NiLCl2] and [Zn3L2Cl4]Cl2 were prepared. Details are given of the formation of the complex [Cu(L.EtOH)Cl2], in which one molecule of EtOH adds across only one of the Schiff base C=N groups to give the coordinated ligand L.EtOH. The rationalization of this type of reaction by considering the steric requirements of the ligand is given. The complexes were characterized by elemental analyses, conductivity measurements, thermal techniques, mass spectra, magnetic susceptibilities and spectroscopic (i.r., ligand field, e.s.r., H-1 n.m.r.) studies. The nitrogen donor atoms of the tetradentate ligands L and L.EtOH are assumed to adopt an essentially planar arrangement about manganese(II), cobalt(II), nickel(II) and copper(II), with the remaining axial coordination sites occupied by chloro ligands to yield high-spin octahedral molecules. A trinuclear structure, based on tetrahedrally coordinated metal ions, is proposed for the zinc(II) complex.en
heal.publisherSpringer Verlag (Germany)en
heal.journalNameTransition Metal Chemistryen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

Show simple item record
Files in This Item:
File Description SizeFormat 
Kasselouri-1993-Complexes of Divalen.pdf639.78 kBAdobe PDFView/Open    Request a copy
Show simple item record  


This item is licensed under a Creative Commons License Creative Commons