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dc.contributor.authorStergiou, D. V.en
dc.contributor.authorDiamanti, E. K.en
dc.contributor.authorGournis, D.en
dc.contributor.authorProdromidis, M. I.en
dc.date.accessioned2015-11-24T16:54:06Z-
dc.date.available2015-11-24T16:54:06Z-
dc.identifier.issn1388-2481-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10114-
dc.rightsDefault Licence-
dc.subjectgraphene oxideen
dc.subjectchemically-reduced graphene oxideen
dc.subjectgrapheneen
dc.subjectascorbic aciden
dc.subjectelectrochemical sensorsen
dc.subjectoxideen
dc.subjectliquiden
dc.titleComparative study of different types of graphenes as electrocatalysts for ascorbic aciden
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.elecom.2010.07.006-
heal.identifier.secondary<Go to ISI>://000284444500012-
heal.identifier.secondaryhttp://ac.els-cdn.com/S1388248110003024/1-s2.0-S1388248110003024-main.pdf?_tid=7988475fd66ec9f5f44107ca34a34c5c&acdnat=1333037377_c5326ae469bb40e3de631b512fefdb6f-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2010-
heal.abstractA comparative study regarding the electrocatalytic activity of graphene oxide (GO), chemically-reduced graphene oxide (crGO) and graphene produced by direct liquid exfoliation (dG) is presented. Sensors were developed by modifying glassy carbon (GC) electrodes with GO, crGO and dG and ascorbic acid was used as a pilot analyte. GC/GO electrodes offer substantially lower oxidation overpotential, up to 350 mV, compared with GC/crGO, GC/dG and unmodified GC electrodes. In addition, the different carbon-to-oxygen atomic ratios in GO, as it occurs depending on the synthetic route, were found to have a remarkable effect on the performance of the sensors. Reduction of GO was achieved by immersing the modified electrodes into a stirred solution of NaBH(4) for 10 min at room temperature. This process was used alternatively of the time consuming and laborious process of hydrazine, and its effectiveness was confirmed by cyclic voltammetry and electrochemical impedance spectroscopy. Analytical utility of the sensors is demonstrated. (C) 2010 Elsevier B.V. All rights reserved.en
heal.publisherElsevieren
heal.journalNameElectrochemistry Communicationsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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