Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/10044
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dc.contributor.authorGiannakas, A. E.en
dc.contributor.authorLeontiou, A. A.en
dc.contributor.authorLadavos, A. K.en
dc.contributor.authorPomonis, P. J.en
dc.date.accessioned2015-11-24T16:53:37Z-
dc.date.available2015-11-24T16:53:37Z-
dc.identifier.issn0926-860X-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10044-
dc.rightsDefault Licence-
dc.subjectperovskitesen
dc.subjectceen
dc.subjectsren
dc.subjectno plus coen
dc.subjectreverse microemulsionen
dc.subjectmixed oxidesen
dc.subjectoxidationen
dc.subjectlamno3en
dc.subjectfeen
dc.subjectsubstitutionen
dc.subjectreductionen
dc.subjectcomplexen
dc.subjectoxygenen
dc.titleCharacterization and catalytic investigation of NO plus CO reaction on perovskites of the general formula LaxM1-xFeO3 (M = Sr and/or Ce) prepared via a reverse micelles microemulsion routeen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.apcata.2006.05.016-
heal.identifier.secondary<Go to ISI>://000239288800012-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0926860X06003887/1-s2.0-S0926860X06003887-main.pdf?_tid=2d94cdb2d0ae1d1e6b85ba563bcfdb3b&acdnat=1333036286_559d0a2eb343859c1842dd1519304f9a-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2006-
heal.abstractFour different perovskite type solids with nominal composition LaFeO3 (LFOr), La0.85Sr0.15FeO3 (LSFOr), La0.8Sr0.1Ce0.1FeP3 (LSCFOr) and La0.8Ce0.2FeO3 (LCFOr) were prepared via a reverse micelles microemulsion route. The aim of this work was to investigate the effect of doping with Sr and Ce in the structural properties, surface area and catalytic properties of final solids in comparison with the undoped reference solid LaFeO3. The microemulsion system which was used is composed of cetyl-trimethyl-ammonium-bromide (CTAB), 1-butanol, n-octane and nitrate salts of the metals. XRD measurements combined with Rietveld analysis helped us to identify the % quantity of structural phases which were formed. Scanning electron microscopy (SEM) images showed that the obtained solids consist of nanoparticles in the range of 20-80 run. BET experiments showed that-the final solids achieve much higher specific surface area (ssa) (30-61 m(2)/g) than similar solids which have been prepared by other methods. Catalytic tests in NO + CO reaction were made with the use of gases He/NO/CO in the ratio 96/2/2 with a total flow rate of 100 cm(3)/min. The full sequence of catalytic activity of tested solids is LCFOr > LSCFOr > LSFOr > LFOr and this sequence is in full agreement with the sequence of increment of ssa of the solids. (C) 2006 Elsevier B.V. All rights reserved.en
heal.publisherElsevieren
heal.journalNameApplied Catalysis a-Generalen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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