Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/10025
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dc.contributor.authorBokaris, E. P.en
dc.contributor.authorSiskos, M. G.en
dc.contributor.authorZarkadis, A. K.en
dc.date.accessioned2015-11-24T16:53:29Z-
dc.date.available2015-11-24T16:53:29Z-
dc.identifier.issn0014-3057-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10025-
dc.rightsDefault Licence-
dc.subjectethylene polymerizationen
dc.subjecttitaniumen
dc.subjectmetathesisen
dc.titleCationic Transannular Polymerization of 1,5-Cyclooctadiene by Cp2mcl2 (M = Ti, Zr or Hf) Ziegler-Natta Catalysts with Et3al, Et2alcl and Et3al2cl3 as Cocatalystsen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1016/0014-3057(92)90289-E-
heal.identifier.secondary<Go to ISI>://A1992JX54900020-
heal.identifier.secondaryhttp://ac.els-cdn.com/001430579290289E/1-s2.0-001430579290289E-main.pdf?_tid=bfb1ef06-356f-11e3-9f33-00000aacb360&acdnat=1381824162_d1a4ee90f0dbe0927752e20965f01340-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate1992-
heal.abstractThe cationic transannular polymerization of cis,cis-1,5-cyclooctadiene (COD) initiated by Ziegler-Natta catalysts of the type Cp2MCl2 (M = Ti, Zr, Hf) with various alkylaluminium compounds, such as Et3Al, Et2AlCl and Et3Al2Cl3, was studied. The order of activity of these catalysts depends on the metal and the cocatalyst and was found to be: Ti > Zr > Hf and Et3Al2Cl3 > Et2AlCl > Et3Al. M(w)BAR of the resulting oligomers are approximately 800-1800. By means of H-1-NMR, i.r., GPC and TG/DTG analyses, the transannular character of the polymers was also confirmed.en
heal.publisherElsevieren
heal.journalNameEuropean Polymer Journalen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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