Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/10010
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dc.contributor.authorV. -C. Arunasalam,en
dc.contributor.authorD. M. P. Mingos,en
dc.contributor.authorJ. C. Plakatouras,en
dc.contributor.authorI. Baxter,en
dc.contributor.authorM. B. Hursthouse,en
dc.contributor.authorK. M. A. Maliken
dc.date.accessioned2015-11-24T16:53:24Z-
dc.date.available2015-11-24T16:53:24Z-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10010-
dc.rightsDefault Licence-
dc.titleCarbonyl sulfide insertion reactions into metal-alkoxide bonds. Synthesis and molecular structure of di[bis(methylthiocarbonato)tris (methanol)calcium]en
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.secondaryhttp://www.sciencedirect.com/science/article/pii/027753879500034P-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate1995-
heal.abstractThe reaction of COS gas with a suspension of [M(OMe)2]Ξ· (M = Mg and Ca) in methanol yields the insertion compounds, [M(OCSOMe)2(MeOH)x]Ξ· (M = Mg 1, View the MathML source) in high yield; the magnesium compound is polymeric, whilst X-ray crystallography reveals that the calcium complex 2 is a centrosymmetric dimer with eight coordinated calcium(II) ions and two distinct methylthiocarbonato (MTC) ligand coordinations modes, the structural framework being stabilised by an extensive network of hydrogen bonding.en
heal.publisherElsevieren
heal.journalNamePolyhedronen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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