Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/14609
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dc.contributor.authorTulyaganov, D. U.en
dc.contributor.authorAgathopoulos, S.en
dc.contributor.authorVentura, J. M.en
dc.contributor.authorKarakassides, M. A.en
dc.contributor.authorFabrichnaya, O.en
dc.contributor.authorFerreira, J. M. F.en
dc.date.accessioned2015-11-24T17:39:12Z-
dc.date.available2015-11-24T17:39:12Z-
dc.identifier.issn0955-2219-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14609-
dc.rightsDefault Licence-
dc.subjectsinteringen
dc.subjectcrystallizationen
dc.subjectmicrostructure-finalen
dc.subjectglassen
dc.subjectglass-ceramicsen
dc.subjectsilicate-glassesen
dc.subjectnucleating-agentsen
dc.subjectborate glassesen
dc.subjectcrystallizationen
dc.subjectalkalineen
dc.subjectwastesen
dc.subjectkiraen
dc.titleSynthesis of glass-ceramics in the CaO-MgO-SiO2 system with B2O3, P2O5, Na2O and CaF2 additivesen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.jeurceramsoc.2005.02.009-
heal.identifier.secondary<Go to ISI>://000236649800020-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0955221905001378/1-s2.0-S0955221905001378-main.pdf?_tid=41835ab2c0112bac683ba4ccead5a3e5&acdnat=1339492565_e5eb0e2d01d758fcbe4d882cb01305da-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.publicationDate2006-
heal.abstractGlass-ceramics based on the CaO-MgO-SiO2 system with limited amount of additives (B2O3, P2O5, Na2O and CaF2) were prepared. All the investigated compositions were melted at 1400 degrees C for 1 h and quenched in air or water to obtain transparent bulk or frit glass, respectively. Raman spectroscopy revealed that the main constituents of the glass network are the silicates Q(1) and Q(2) units. Scanning electron microscopy (SEM) analysis confirmed liquid-liquid phase separation and that the glasses are prone to surface crystallization. Glass-ceramics were produced via sintering and crystallization of glass-powder compacts made of milled glass-frit (mean particle size 11-15 mu m). Densification started at 620-625 degrees C and was almost complete at 700 degrees C. Crystallization occurred at temperatures > 700 degrees C. Highly dense and crystalline materials, predominantly composed of diopisde and wollastonite together with small amounts of akermanite and residual glassy phase, were obtained after heat treatment at 750 degrees C and 800 degrees C. The glass-ceramics prepared at 800 degrees C exhibited bending strength of 116-141 MPa, Vickers microhardness of 4.53-4.65 GPa and thermal expansion coefficient (100-500 degrees C) of 9.4-10.8 x 10(-6) K-1. (c) 2005 Elsevier Ltd. All rights reserved.en
heal.publisherElsevieren
heal.journalNameJournal of the European Ceramic Societyen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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