Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/14599
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dc.contributor.authorGrana, E.en
dc.contributor.authorKatsigiannopoulos, D.en
dc.contributor.authorAvgeropoulos, A.en
dc.contributor.authorGoulas, V.en
dc.date.accessioned2015-11-24T17:39:09Z-
dc.date.available2015-11-24T17:39:09Z-
dc.identifier.issn1023-666X-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14599-
dc.rightsDefault Licence-
dc.subjectblock copolymers-terpolymeren
dc.subjectoxidation-anionic polymerizationen
dc.subjectpolythiopheneen
dc.subjectstar homopolymeren
dc.titleSynthesis and molecular characterization of polythiophene block co-, ter-polymers and four-arm star homopolymeren
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1080/10236660801905692-
heal.identifier.secondary<Go to ISI>://000255064400003-
heal.identifier.secondaryhttp://www.tandfonline.com/doi/pdf/10.1080/10236660801905692-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.publicationDate2008-
heal.abstractWe report the synthesis of polythiophene (PT) block copolymers with polystyrene (PS) or polyisoprene of increased 3,4 microstructure (PI3,4) and triblock terpolymer of the PS-b-PI-b-PT type. Tetrathienylsilane (C16H12S4Si) was also prepared in order to react with thiophene and eventually synthesize a four-arm star PT homopolymer. The preparation of the functional precursors and intermediate products (PS, PI, PS-b-P-13,P-4, and C16H12S4Si) was achieved through high vacuum techniques, and PT was synthesized under ambient conditions via the corresponding chemical oxidative polymerization reaction. The final polymers and the intermediate precursors were molecularly characterized by size exclusion chromatography (SEC), membrane osmometry (MO), proton nuclear magnetic resonance (H-1-NMR), and carbon nuclear magnetic resonance (C-13-NMR) spectroscopies.en
heal.publisherTaylor & Francisen
heal.journalNameInternational Journal of Polymer Analysis and Characterizationen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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