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Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/14420
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dc.contributor.authorFokas, D.en
dc.contributor.authorOrgueira, H.en
dc.contributor.authorIsome, Y.en
dc.contributor.authorBaldino, C. M.en
dc.contributor.authorChan, A. S.en
dc.date.accessioned2015-11-24T17:37:56Z-
dc.date.available2015-11-24T17:37:56Z-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14420-
dc.rightsDefault Licence-
dc.subjectCu(I) generated in situen
dc.subjectTriazolesen
dc.subjectRegioselectivesynthesisen
dc.titleRegioselective Synthesis of [1,2,3]-Triazoles Catalyzed by Cu(I) Generated in situ from Cu(0) Nanosize Activated Powder and Amine Hydrochloride Saltsen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryhttp://dx.doi.org/10.1016/j.tetlet.2005.02.127-
heal.identifier.secondaryhttp://www.sciencedirect.com/science/article/pii/S0040403905004363-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.publicationDate2005-
heal.abstractA straightforward and efficient method for the regioselectivesynthesis of functionalized 1,4-disubstituted [1,2,3]-triazoles, from terminal alkynes and azides, has been established utilizing Cu(0) as the source of the catalytic species. The presumed catalytic Cu(I) species is generated by the combination of 10 mol % copper nanosizeactivatedpowder and 1 equiv of an aminehydrochloridesalt. The addition of an aminehydrochloridesalt into the reaction mixture enhanced the dissolution of copper metal, and subsequently facilitated the formation of the Cu(I)-acetylide intermediate required for the regioselective cycloaddition.en
heal.publisherElsevieren
heal.journalNameTetrahedron Letten
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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