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dc.contributor.authorKarakassides, M. A.en
dc.contributor.authorSaranti, A.en
dc.contributor.authorKoutselas, I.en
dc.date.accessioned2015-11-24T17:37:33Z-
dc.date.available2015-11-24T17:37:33Z-
dc.identifier.issn0022-3093-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14372-
dc.rightsDefault Licence-
dc.subjectcrystal-structureen
dc.subjectraman-spectroscopyen
dc.subjectmgo-p2o5 glassesen
dc.subjectceramicsen
dc.subjectboneen
dc.subjectphaseen
dc.subjectcrystallizationen
dc.subjectscatteringen
dc.subjectsystemen
dc.subjectnmren
dc.titlePreparation and structural study of binary phosphate glasses with high calcium and/or magnesium contenten
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.jnoncrysol.2004.08.111-
heal.identifier.secondary<Go to ISI>://000225555600010-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0022309304007112/1-s2.0-S0022309304007112-main.pdf?_tid=991f9689553009c6f6eeb4e69dc5a9cc&acdnat=1339493351_98667802438af300c394a3f770243b2a-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.publicationDate2004-
heal.abstractGlasses of high CaO or MgO content in the systems xCaO(1 - x)P2O5 (0.50 less than or equal to x less than or equal to 0.72) and xMgO(1 - x)P2O5 (0.50 less than or equal to x less than or equal to 0.80) have been prepared for the first time using a twin roller device and studied by Raman spectroscopy. It has been shown that the structure of glasses depends on the type of alkali earth cation; the modification of the phosphate network is higher for the Ca containing glasses with respect to the Mg ones, at the same alkali earth content, due to the well defined Ca properties as a modifying cation. X-ray diffraction patterns of the thermally treated at 850 degreesC calcium containing glasses show precipitation of bioactive crystalline phases, such as beta-Ca-3(PO4)(2) and beta-Ca2P2O7. The molecular dynamics simulations have provided insight for the high Mg and Ca content phosphate glasses formation, where their average oxygen coordination number is calculated as five and six for all glass compositions studied, respectively. (C) 2004 Elsevier B.V. All rights reserved.en
heal.publisherElsevieren
heal.journalNameJournal of Non-Crystalline Solidsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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