Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/14289
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dc.contributor.authorPinakidou, F.en
dc.contributor.authorKatsikini, M.en
dc.contributor.authorPatsalas, P.en
dc.contributor.authorAbadias, G.en
dc.contributor.authorPaloura, E. C.en
dc.date.accessioned2015-11-24T17:36:50Z-
dc.date.available2015-11-24T17:36:50Z-
dc.identifier.issn1662-5250-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14289-
dc.rightsDefault Licence-
dc.subjectexafsen
dc.subjectnexafsen
dc.subjectshort-range orderen
dc.subjecttin-coatingsen
dc.subjectticu filmsen
dc.subjectx-ray-absorptionen
dc.subjectsuperhard nanocomposite coatingsen
dc.subjectthin-filmsen
dc.subjectmechanical-propertiesen
dc.subjectedge spectroscopyen
dc.subjectfine-structureen
dc.subjectcopperen
dc.subjectsuperconductorsen
dc.subjectoxidaseen
dc.subjectionen
dc.titleOn the Nanostructure of Cu in TixCu1-x and TiN/Cu Films: a XAFS Studyen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.secondary<Go to ISI>://000271239000006-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.publicationDate2009-
heal.abstractThe effect of chemical composition on the bonding environment of Cu, in a series of Ti1-x Cu-x and TiN/Cu films, is studied using X-Ray Absorption Spectroscopies (XAFS) at the Cu-K-edge. The EXAFS analysis reveals that in all studied samples Cu is amorphous. However, its bonding environment depends on the chemical composition. More specifically, in the Ti1-xCux films, Cu is coordinated with Ti and Cu and belongs both to intermetallic TiCu and to an amorphous Cu matrix. The coordination number of Cu, i.e., the sum of Ti and Cu first neighbours, increases systematically from 6.3 +/- 0.7 to 10.6 +/- 0.9 when the Cu content increases from 24.1 to 52.7 at%. On the contrary, in the TiN/Cu films, the type of atoms that consists the 1(st) nearest neighbour shell of Cu varies as a function of the Cu concentration. More specifically, in the TiN/Cu film with the lowest Cu content (27.3 at%), intermetallic TiCu is detected. At intermediate Cu concentration (37.8 at%), Cu is bonded to both Ti and Cu atoms. Finally, in the TiN/Cu film with the highest Cu content (67.7 at%), Cu is metallic.en
heal.publisherTrans Tech Publications Ltden
heal.journalNameJournal of Nano Researchen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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