Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/14249
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dc.contributor.authorSerrano, E.en
dc.contributor.authorTercjak, A.en
dc.contributor.authorKortaberria, G.en
dc.contributor.authorPomposo, J. A.en
dc.contributor.authorMecerreyes, D.en
dc.contributor.authorZafeiropoulos, N. E.en
dc.contributor.authorStamm, M.en
dc.contributor.authorMondragon, I.en
dc.date.accessioned2015-11-24T17:36:27Z-
dc.date.available2015-11-24T17:36:27Z-
dc.identifier.issn0024-9297-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14249-
dc.rightsDefault Licence-
dc.subjectmechanical-propertiesen
dc.subjectepoxy-resinen
dc.subjectphase-behavioren
dc.subjecttriblock copolymersen
dc.subjectnatural-rubberen
dc.subjectdiamine blendsen
dc.subjectpolymer blendsen
dc.subjectmorphologyen
dc.subjectcompatibilizationen
dc.subjectcrystallizationen
dc.titleNanostructured thermosetting systems by modification with epoxidized styrene-butadiene star block copolymers. Effect of epoxidation degreeen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1021/Ma0515477-
heal.identifier.secondary<Go to ISI>://000236314800037-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.publicationDate2006-
heal.abstractNovel epoxy-based blends containing 30 wt % star styrene-b-butadiene block copolymers epoxidized at several degrees (SepB) have been investigated in order to analyze the effect of epoxidation degree on the ability of these copolymers to produce nanostructures inside the epoxy matrix as well as their effect on the network structure of the matrix. For neat styrene - butadiene (SB) and SepB15-modified systems, macroscopic phase separation was observed. The SepB epoxidized at 40-76 mol %, however, yielded hexagonally ordered nanostructures formed by PS cylinders arranged in the matrix containing also the epoxidized and nonepoxidized butadiene units. DSC analysis indicates that the slight differences observed in self-assembling of the mixture containing the 40 wt % epoxidized block copolymer with respect to those for the blends with higher epoxidation degrees could be related with reactivity differences of the epoxidized copolymers with the curing agent. It is envisaged that these novel nanostructured blends may lead to novel materials with excellent optical properties and enhanced fracture toughness.en
heal.publisherAmerican Chemical Societyen
heal.journalNameMacromoleculesen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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