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Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/14053
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dc.contributor.authorGournis, D.en
dc.contributor.authorGeorgakilas, V.en
dc.contributor.authorKarakassides, M. A.en
dc.contributor.authorBakas, T.en
dc.contributor.authorKordatos, K.en
dc.contributor.authorPrato, M.en
dc.contributor.authorFanti, M.en
dc.contributor.authorZerbetto, F.en
dc.date.accessioned2015-11-24T17:34:55Z-
dc.date.available2015-11-24T17:34:55Z-
dc.identifier.issn0002-7863-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14053-
dc.rightsDefault Licence-
dc.subjectraman-spectraen
dc.subjectenergy minimizationen
dc.subjectmolecular-dynamicsen
dc.subjectforce-fielden
dc.subjectbuckminsterfullereneen
dc.subjectc-60en
dc.subjectintercalationen
dc.subjectmacrocyclesen
dc.subjectconfinementen
dc.subjecttransitionen
dc.titleIncorporation of fullerene derivatives into smectite clays: A new family of organic-inorganic nanocompositesen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1021/Ja049237b-
heal.identifier.secondary<Go to ISI>://000222612600044-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.publicationDate2004-
heal.abstractThree fulleropyrrolidine derivatives, characterized by the presence of positive charges, were introduced in the interlayer space of montmorillonite. The composites were characterized by powder X-ray diffraction and differential thermal and thermogravimetric (DTA-TGA) analysis, in conjunction with FTIR, UV-Vis, Raman, and Fe-57-Mossbauer spectroscopies. Organophilic derivatives were intercalated into organically modified clays, while water-soluble fulleropyrrolidines were introduced into the clay galleries through ion exchange. The experiments, complemented by computer simulations, show that not all the clay-clay platelets are intercalated by the fullerene derivatives and that a sizable amount of charge transfer takes place between the host and the guests.en
heal.publisherAmerican Chemical Societyen
heal.journalNameJ Am Chem Socen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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