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dc.contributor.authorSakellariou, G.en
dc.contributor.authorAvgeropoulos, A.en
dc.contributor.authorHadjichristidis, N.en
dc.contributor.authorMays, J. W.en
dc.contributor.authorBaskaran, D.en
dc.date.accessioned2015-11-24T17:34:33Z-
dc.date.available2015-11-24T17:34:33Z-
dc.identifier.issn0032-3861-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/13991-
dc.rightsDefault Licence-
dc.subjectnanoparticlesen
dc.subjectsurface-functionalizationen
dc.subjectdiblock copolymersen
dc.subjectpolystyrene nanoparticlesen
dc.subjectnanostructuresen
dc.subjectmacromoleculesen
dc.subjectpolymerizationen
dc.subjectarchitectureen
dc.titleFunctionalized organic nanoparticles from core-crosslinked poly(4-vinylbenzocyclobutene-b-butadiene) diblock copolymer micellesen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.polymer.2009.10.038-
heal.identifier.secondary<Go to ISI>://000272654100003-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0032386109009161/1-s2.0-S0032386109009161-main.pdf?_tid=d3cb6da2f47efa28126050bd7b790e9e&acdnat=1339489666_25c4ba0249ffcf4c4b7751044598eda3-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.publicationDate2009-
heal.abstractSurface-functionalized polymeric nanoparticles were prepared by: a) self-assembly of poly(4-vinyl-benzocyclobutene-b-butadiene) diblock copolymer (PVBCB-b-PB) to form spherical micelles (diameter: 15-48 nm) in decane, a selective solvent for PB, b) crosslinking of the PVBCB core through thermal dimerization at 200-240 degrees C, and c) cleavage of the PB corona via ozonolysis and addition of dimethyl sulfide to afford aldehyde-functionalized nanoparticles (diameter: similar to 16-20 nm), along with agglomerated nanoparticles ranging from similar to 30 to similar to 100 nm in diameter. The characterization of the diblock copolymer precursors, the intermediate micelles and the final surface-functionalized crosslinked nanoparticles was carried out by a combination of size exclusion chromatography, static and dynamic light scattering, viscometry, thermogravimetric analysis, (1)H NMR and FTIR spectroscopy and transmission electron rnicroscopy. Published by Elsevier Ltd.en
heal.publisherElsevieren
heal.journalNamePolymeren
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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