Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/13962
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dc.contributor.authorLin, D. J.en
dc.contributor.authorBeltsios, K.en
dc.contributor.authorChang, C. L.en
dc.contributor.authorCheng, L. P.en
dc.date.accessioned2015-11-24T17:34:26Z-
dc.date.available2015-11-24T17:34:26Z-
dc.identifier.issn0887-6266-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/13962-
dc.rightsDefault Licence-
dc.subjectpoly(vinylidene fluoride)en
dc.subjectphase-inversion membranesen
dc.subjectcrystallizationen
dc.subjectmorphologyen
dc.subjectspheruliteen
dc.subjectimmersion-precipitationen
dc.subjectmorphologyen
dc.subjectsystemsen
dc.subjectcrystallizationen
dc.subjectseparationen
dc.subjectpolyethyleneen
dc.subject1-octanolen
dc.subjectpolymersen
dc.subjectbehavioren
dc.subjectspheresen
dc.titleFine structure and formation mechanism of particulate phase-inversion poly(vinylidene fluoride) membranesen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1002/Polb.10513-
heal.identifier.secondary<Go to ISI>://000183564000016-
heal.identifier.secondaryhttp://onlinelibrary.wiley.com/store/10.1002/polb.10513/asset/10513_ftp.pdf?v=1&t=h3fkedpj&s=26b2385a55932643b600db3c7b0893645d868331-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.publicationDate2003-
heal.abstractThe structure and formation mechanism of a microporous phase-inversion poly(vinylidene fluoride) (PVDF) membrane exhibiting a relatively loosely packed agglomerate of semicrystalline globules are explored. The membrane has been prepared by the coagulation of a solution of PVDF in dimethylformamide by the action of 1-octanol, which is a soft nonsolvent. Experimental observations pertain to the globule surface, which is dominated by a grainy nanostructure; the globular interior, which exhibits a range of fine structures (e.g., twisted sheets and treelike branches); and the globule-globule connections, which exhibit a sheetlike or ropelike structure. On the basis of the observed structural details and phase diagram considerations, it is proposed that the membrane structure is the result of a unique combination of a polymer crystallization and a liquid-liquid phase-separation process, with end-result globular structural features of remarkable uniformity. (C) 2003 Wiley Periodicals, Inc.en
heal.publisherWileyen
heal.journalNameJournal of Polymer Science Part B-Polymer Physicsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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