Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/13936
Full metadata record
DC FieldValueLanguage
dc.contributor.authorGournis, D.en
dc.contributor.authorLappas, A.en
dc.contributor.authorKarakassides, M. A.en
dc.contributor.authorTobbens, D.en
dc.contributor.authorMoukarika, A.en
dc.date.accessioned2015-11-24T17:34:11Z-
dc.date.available2015-11-24T17:34:11Z-
dc.identifier.issn0342-1791-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/13936-
dc.rightsDefault Licence-
dc.subjectmontmorilloniteen
dc.subjectneutron diffractionen
dc.subjectlithium migrationen
dc.subjectinfrared reflectanceen
dc.subjecthoffman klemen effecten
dc.subjectheated montmorilloniteen
dc.subjectisotopic-substitutionen
dc.subjectinfrared reflectanceen
dc.subjectli-montmorillonitesen
dc.subjectchargeen
dc.subjectclayen
dc.subjectlithiumen
dc.subjectsmectitesen
dc.subjectnuclearen
dc.subjecttemperatureen
dc.titleA neutron diffraction study of alkali cation migration in montmorillonitesen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1007/s00269-007-0197-z-
heal.identifier.secondary<Go to ISI>://000251796500006-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.publicationDate2008-
heal.abstractNeutron powder diffraction measurements on lithium and cesium saturated montmorillonite samples before and after heat treatment at 300 degrees C are studied, in order to undertake a complete refinement of crystal structure and unravel the migration mechanism for the interlayer cations of Li or Cs. Rietveld analysis of the corresponding diffraction patterns finds that montmorillonite crystallizes in the C2/m space group with unit cell dimensions consistent with the size of the specific interlayer cation. We show that thermal treatment affects the two types of samples in a different way. This is with respect to their unit cell dimensions and the migration of Li from the 2b to the 2c clay lattice site, in constrast to the Cs positioning which remains effectively unchanged.en
heal.publisherSpringer-Verlagen
heal.journalNamePhysics and Chemistry of Mineralsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

Files in This Item:
File Description SizeFormat 
Gournis-2008-A neu.pdf1.53 MBAdobe PDFView/Open    Request a copy


This item is licensed under a Creative Commons License Creative Commons