Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/13867
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dc.contributor.authorLin, D. J.en
dc.contributor.authorChang, H. H.en
dc.contributor.authorBeltsios, K.en
dc.contributor.authorDon, T. M.en
dc.contributor.authorJeng, Y. S.en
dc.contributor.authorCheng, L. P.en
dc.date.accessioned2015-11-24T17:33:30Z-
dc.date.available2015-11-24T17:33:30Z-
dc.identifier.issn0887-6266-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/13867-
dc.rightsDefault Licence-
dc.subjectannealingen
dc.subjectmelting pointen
dc.subjectmembranesen
dc.subjectmicrostructureen
dc.subjectx-rayen
dc.subjecthollow-fiber membranesen
dc.subjectformation mechanismen
dc.subjectcoagulation bathen
dc.subjectfine-structureen
dc.subjectmorphologyen
dc.subjectpvdfen
dc.subjecttemperatureen
dc.subjectcrystallinityen
dc.subjectpolymersen
dc.subjectprecipitationen
dc.titleEffect of Postcasting Heat-Treatment on the Structure and Properties of Semicrystalline Phase-Inversion Poly(vinylidene fluoride) Membranesen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1002/Polb.21791-
heal.identifier.secondary<Go to ISI>://000270000200004-
heal.identifier.secondaryhttp://onlinelibrary.wiley.com/store/10.1002/polb.21791/asset/21791_ftp.pdf?v=1&t=h3fkcw80&s=b9280e05d449094ba59368168e463cf191d46897-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.publicationDate2009-
heal.abstractMicroPorous PVDF membranes were prepared by immersion-precipitation in 1-octanol of casting dopes dissolved at different temperatures, with dissolution temperature affecting strongly the membrane microstructure. The effect of postcoagulation thermal annealing, which is an additional thermal parameter, on membrane microstructure and properties is probed herein. Membranes obtained were annealed at temperatures up to 160 degrees C, which is close to the melting point of PVDF polymer. Annealing leads to a substantial modification of the nano-scale fine structure of the membranes, while the overall-microporous structure is preserved. At elevated annealing temperatures, nano-grains, fibrils, and stick-like crystalline entities gradually eclipse, while globules develop more robust connections based on wide bands of crystal elements. Probing by X-ray diffraction and dynamic scanning calorimetry shows that crystallinity increases when annealing temperature and time are increased. As regards mechanical properties, the tensile strength of the membranes can be enhanced substantially, up to about 10 times, upon appropriate high temperature prolonged annealing. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 1880-1893, 2009en
heal.publisherWileyen
heal.journalNameJournal of Polymer Science Part B-Polymer Physicsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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