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Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/13797
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dc.contributor.authorSerrano, E.en
dc.contributor.authorTercjak, A.en
dc.contributor.authorOcando, C.en
dc.contributor.authorLarranaga, M.en
dc.contributor.authorParellada, M. D.en
dc.contributor.authorCorona-Galvan, S.en
dc.contributor.authorMecerreyes, D.en
dc.contributor.authorZafeiropoulos, N. E.en
dc.contributor.authorStamm, M.en
dc.contributor.authorMondragon, I.en
dc.date.accessioned2015-11-24T17:32:56Z-
dc.date.available2015-11-24T17:32:56Z-
dc.identifier.issn1022-1352-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/13797-
dc.rightsDefault Licence-
dc.subjectepoxidized sb block copolymersen
dc.subjectfractureen
dc.subjectkineticsen
dc.subjectrheologyen
dc.subjectthermosetting epoxiesen
dc.subjectoxide) triblock copolymersen
dc.subjectcross-linking polymeren
dc.subjectblock-copolymersen
dc.subjectepoxy-resinen
dc.subjectgel pointen
dc.subjectmechanical-propertiesen
dc.subjectphase-behavioren
dc.subjectpoly(epsilon-caprolactone)-epoxy blendsen
dc.subjectcrystallization kineticsen
dc.subjectmicrodomain structureen
dc.titleCuring behavior and final properties of nanostructured thermosetting systems modified with epoxidized styrene-butadiene linear diblock copolymersen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1002/macp.200700169-
heal.identifier.secondary<Go to ISI>://000251010000001-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.publicationDate2007-
heal.abstractNanostructured thermosetting materials based on thermosetting matrices were prepared by modification of an epoxy system with linear PS-block-PB copolymers. The nanostructured thermosets were obtained through PS block segregation. Depending on the block-copolymer content in the thermosets and its epoxidation degree, the PS domains can display micellar, worm-like or hexagonally-packed cylinder structures, retaining the stiffness of the epoxy matrix, where the hexagonally cylindrical morphology lead to a significant increase in fracture toughness. The rheokinetics of micro-phase separation during network formation was investigated. Nanostructures are judged to be formed by polymerization-induced microphase separation, in marked contrast to equilibrium self-organized structures that are preformed, with the microphases fixed via a curing reaction.en
heal.publisherWiley-VCH Verlagen
heal.journalNameMacromolecular Chemistry and Physicsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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