Heterogenation of water-sensitive organometallic catalysts into layered aluminosilicates (Journal article)

Skordilis, C. S./ Pomonis, P. J.

Non-aqueous intercalation of montmorillonite with the water-sensitive species [Mn3O(CH3COO)(6)pyr(3)] was achieved with the use of nitromethane as solvent. The adsorption of the complex into the clay was studied photometrically and follows second order kinetics. Thermogravimetric analysis showed that the complex is adsorbed in excess of the CEC of the clay. XRD measurements suggest that the complex is intercalated parallel to the sheets. The surface area of the fired solids is rather low, due the small height of the formed MnOx pillars.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: metal-complexes,clay catalysts,pillared-clay,montmorillonite,intercalation,hydrogenation,silicates
URI: https://olympias.lib.uoi.gr/jspui/handle/123456789/8081
ISSN: 1381-1169
Link: <Go to ISI>://A1996UR98100021
http://ac.els-cdn.com/1381116995001727/1-s2.0-1381116995001727-main.pdf?_tid=f47186f4dcf0767dff2d453e50084999&acdnat=1333036715_f2d7892f38f4cc9e47d7abd1ab157d5b
Publisher: Elsevier
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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