Ascorbic acid acts as a hydride donor towards 2-arsonocarboxylic acids (Journal article)

Ioannou, P. V./ Siskos, M. G.


2-Arsonohexanoic acid is decomposed during its attempted reduction to 2-arsenosohexanoic acid by triphenylphosphine in the presence of a catalytic amount of iodine. When ascorbic acid is substituted for the triphenylphosphine, hexanoic acid is obtained, implying that the arscorbic acid acts as a hydride donor. Copyright (C) 2001 John Wiley & Sons, Ltd.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: arsonic acids,2-arsonocarboxylic acids,ascorbic acid,hydride transfer,triphenylphosphine,reduction,mechanism,reduction
URI: http://olympias.lib.uoi.gr/jspui/handle/123456789/9925
ISSN: 0268-2605
Link: <Go to ISI>://000168897900009
http://onlinelibrary.wiley.com/store/10.1002/aoc.187/asset/187_ftp.pdf?v=1&t=h0e1mxpe&s=e06dfd02f59fcc897c421ef1a4de8e90a4b7d472
Publisher: Wiley
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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