Ascorbic acid acts as a hydride donor towards 2-arsonocarboxylic acids (Journal article)

Ioannou, P. V./ Siskos, M. G.

2-Arsonohexanoic acid is decomposed during its attempted reduction to 2-arsenosohexanoic acid by triphenylphosphine in the presence of a catalytic amount of iodine. When ascorbic acid is substituted for the triphenylphosphine, hexanoic acid is obtained, implying that the arscorbic acid acts as a hydride donor. Copyright (C) 2001 John Wiley & Sons, Ltd.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: arsonic acids,2-arsonocarboxylic acids,ascorbic acid,hydride transfer,triphenylphosphine,reduction,mechanism,reduction
ISSN: 0268-2605
Link: <Go to ISI>://000168897900009
Publisher: Wiley
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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