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dc.contributor.authorManos, M. J.en
dc.contributor.authorKanatzidis, M. G.en
dc.date.accessioned2015-11-24T16:52:05Z-
dc.date.available2015-11-24T16:52:05Z-
dc.identifier.issn0020-1669-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9826-
dc.rightsDefault Licence-
dc.subjectnonlinear-optical responseen
dc.subjectclustersen
dc.subjectsulfideen
dc.subjectpolychalcogenideen
dc.subjectsemiconductorsen
dc.subjectchemistryen
dc.subjectaerogelsen
dc.subjectcomplexen
dc.subjectsaltsen
dc.subjectbanden
dc.titleUse of Hydrazine in the Hydrothermal Synthesis of Chalcogenides: the Neutral Framework Material [Mn2SnS4(N2H4)(2)]en
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1021/Ic900517u-
heal.identifier.secondary<Go to ISI>://000266428100023-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdfplus/10.1021/ic900517u-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2009-
heal.abstractThe reaction system Mn/Sn/S/hydrazine/water at similar to 150 degrees C afforded [Mn2SnS4(N2H4)(2)] (1). The compound has a unique neutral three-dimensional framework with bridging hydrazine ligands and a variety of interconnectivity modes between MnL6 (L = N, S) octahedra. The complex structure of 1 leads to strong antiferromagnetic interactions between the Mn2+ centers and ordering at similar to 41 K. The stabilization of 1 underscores the high potential of hydrazine to promote the formation of novel chalcogenide materials under solvothermal conditions.en
heal.publisherAmerican Chemical Societyen
heal.journalNameInorg Chemen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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