Unprecedented Ultra-High-Resolution Hydroxy Group (1)H NMR Spectroscopic Analysis of Plant Extracts (Journal article)

Charisiadis, P./ Primikyri, A./ Exarchou, V./ Tzakos, A./ Gerothanassis, I. P.

A general method is demonstrated for obtaining ultra-high resolution in the phenolic hydroxy group (1)H NMR spectroscopic region, in DMSO-d(6) solution, with the addition of picric acid. Line-width reduction by a factor of over 100 was observed, which resulted in line-widths ranging from 1.6 to 0.6 Hz. This unprecedented resolution, in combination with the shielding sensitivity of the hydroxy group absorptions to substituent effects at least up to 11 bonds distant and the application of 2D (1)H-(13)C HMBC techniques, allows the unequivocal structure analysis of natural products with phenolic hydroxy groups in complex plant extracts.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: magnetic-resonance spectroscopy,charge-transfer complexes,acids,quantification,mixtures,exchange,cancer,media
URI: https://olympias.lib.uoi.gr/jspui/handle/123456789/9812
ISSN: 0163-3864
Link: <Go to ISI>://000297274900021
http://pubs.acs.org/doi/abs/10.1021/np200329a
Publisher: American Chemical Society
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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