Unexpected reduction of vanadium(IV) to vanadium(III) in the presence of the chelate ligands 2,2 '-bipyridine (bpy) and 1,8-hydroxyquinoline (Hquin) (Journal article)

Manos, M. J./ Tasiopoulos, A. J./ Raptopoulou, C./ Terzis, A./ Woollins, J. D./ Slawin, A. M. Z./ Keramidas, A. D./ Kabanos, T. A.

The structures, NMR spectra and electrochemical properties of the vanadium(III) compounds, cis-[(VCl2)-Cl-III(acac)(bpy)] and [V-III(quin)(3)]. 2CH(3)OH, formed from [(VCl2)-Cl-IV(acac)(2)].0.25CH(2)Cl(2) (Hacac=pentane-2,4-dione) and [(VOCl2)-O-IV(thf)(2)] with bpy and Hquin respectively are described as well as the structure of the catecholate dioxovanadium(V) dimer [Et3NH](2)[VO2(mu -dtbc)](2) (H(2)dtbc=3,5-di-tert-butylcatechol).
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: ethanol solvate,blood-cells,complexes,acetonitrile,o-2
URI: http://olympias.lib.uoi.gr/jspui/handle/123456789/9807
ISSN: 1472-7773
Link: <Go to ISI>://000168598300003
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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