The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1,2,3]triazole] (Journal article)

Kostakis, G. E./ Xydias, P./ Nordlander, E./ Plakatouras, J. C.

The reaction of the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1,2,3]triazole] (L) with CuCl2 in acetonitrile yields a dinuclear copper(II) complex [Cu2Cl4L2]center dot 2CH(3)CN (1.2CH3CN), which has been characterized by elemental analysis, powder and single crystal X-ray diffraction, thermal gravimetric analysis as well as IR, UV-Vis and EPR spectroscopy The crystal structure reveals that the metal coordination geometry is best described as square planar. (C) 2011 Elsevier B. V. All rights reserved.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: copper,[1-(4-((1h-benzo[d][1,2,3]triazol-2(3h)-yl)methyl)benzyl)-1h-benzo[d][1,2,3]triazole],complex,x-ray,nonlinear-optical properties,crystal-structure,coordination polymers,corrosion-inhibitors,reaction ratio,benzotriazole,chemistry,dinuclear,product,chain
ISSN: 0020-1693
Link: <Go to ISI>://000300623600049
Publisher: Elsevier
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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