The catalytic activity of immobilized on modified silica metalloporphyrins bearing antioxidative 2,6-di-tert-butylphenol pendants (Journal article)

Milaeva, E. R./ Gerasimova, O. A./ Maximov, A. L./ Ivanova, E. A./ Karachanov, E. A./ Hadjiliadis, N./ Louloudi, M.


A comparative study of the catalytic activity of supported manganese(III) and iron(III) chlorides of meso-tetrakis(3,5-di-tert-butyl-4-hydroxyphenyl)porphyrin (R4PMnCl, R4PFeCl) and meso-tetraphenylporphyrin (TPPMnCl, TPPFeCl) is reported. The metalloporphyrins have been immobilized via coordination bond on the surface of two series of imidazole modified silica, imidazole propyl silica (IPS) and imidazole 3-(glycidyloxypropyl) silica (IGOPS). The heterogenised catalysts have been evaluated for hydrocarbon oxidation by sodium periodate. The critical role of 2,6-di-tert-butylphenol groups on the periphery of porphyrin ring in their catalytic activity has been evaluated and pertinent structural and mechanistic aspects are discussed. (C) 2007 Elsevier B.V. All rights reserved.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: supported metalloporphyrins,2,6-di-tert-butylphenol,biomimetic oxidation,imidazole propyl gel,hydrocarbon monooxygenation catalyst,manganese porphyrin,polyvalent porphyrins,alkane hydroxylation,oxidation catalysts,olefin epoxidation,hydrogen-peroxide,complexes,alkene
URI: http://olympias.lib.uoi.gr/jspui/handle/123456789/9581
ISSN: 1566-7367
Link: <Go to ISI>://000251208900040
http://ac.els-cdn.com/S1566736707001550/1-s2.0-S1566736707001550-main.pdf?_tid=cd3c92ba-362e-11e3-8036-00000aacb360&acdnat=1381906219_388d0a7b697c7f11e43f985193ca5684
Publisher: Elsevier
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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