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https://olympias.lib.uoi.gr/jspui/handle/123456789/9223Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Giokas, D. L. | en |
| dc.contributor.author | Paleologos, E. K. | en |
| dc.contributor.author | Karayannis, M. I. | en |
| dc.date.accessioned | 2015-11-24T16:47:41Z | - |
| dc.date.available | 2015-11-24T16:47:41Z | - |
| dc.identifier.issn | 1618-2642 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9223 | - |
| dc.rights | Default Licence | - |
| dc.subject | iron speciation | en |
| dc.subject | cloud-point extraction | en |
| dc.subject | ferrozine method | en |
| dc.subject | spectrophotometry | en |
| dc.subject | atomic absorption spectrometry | en |
| dc.subject | flow-injection analysis | en |
| dc.subject | atomic-absorption spectrometry | en |
| dc.subject | plasma-mass spectrometry | en |
| dc.subject | iron speciation | en |
| dc.subject | environmental-samples | en |
| dc.subject | coastal rainwater | en |
| dc.subject | water samples | en |
| dc.subject | preconcentration | en |
| dc.subject | iron(iii) | en |
| dc.subject | seawater | en |
| dc.title | Speciation of Fe(II) and Fe(III) by the modified ferrozine method, FIA-spectrophotometry, and flame AAS after cloud-point extraction | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.primary | DOI 10.1007/s00216-002-1326-7 | - |
| heal.identifier.secondary | <Go to ISI>://000177145000007 | - |
| heal.identifier.secondary | http://download.springer.com/static/pdf/380/art%253A10.1007%252Fs00216-002-1326-7.pdf?auth66=1381906175_494ad5993a55f82c99b34b0a1f40a49c&ext=.pdf | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 2002 | - |
| heal.abstract | A method has been developed for the simultaneous determination of traces of Fe(III) and Fe(II) in water by on-line coupling of spectrophotometry with flame atomic absorption spectrometry (FAAS). The method involves cloud-point extraction (CPE) of both species with ammonium pyrrolidinecarbodithioate (APDC) under standard conditions, which facilitates the in situ complexation and extraction of both species. Differentiation of the oxidation states of iron is achieved by using mathematical equations to overcome the interference of Fe(Ill) in the spectrophotometric determination of Fe(Il) when they are both present in the same solution. In this manner the time-consuming and labor-intensive steps of preoxidation of Fe(II) or reduction of Fe(III) are eliminated. By preconcentrating a 10-mL sample solution detection limits as low as 7 mug L-1, were obtained after a single-step extraction procedure. The relative standard deviation (n=4, 30 mug L-1) was 2.6% and 1.8% for spectrophotometry and FAAS, respectively. Recoveries in the range of 96-105% were obtained by analysis of spiked real samples. The method was further verified by analyzing a certified reference material (IMEP-9); for this the recovery was 98.5%. | en |
| heal.publisher | Springer Verlag (Germany) | en |
| heal.journalName | Anal Bioanal Chem | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Giokas-2002-Speciation of Fe(II).pdf | 75.18 kB | Adobe PDF | View/Open Request a copy |
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