Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/9169
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dc.contributor.authorKazos, E. A.en
dc.contributor.authorNanos, C. G.en
dc.contributor.authorStalikas, C. D.en
dc.contributor.authorKonidari, C. N.en
dc.date.accessioned2015-11-24T16:47:21Z-
dc.date.available2015-11-24T16:47:21Z-
dc.identifier.issn0045-6535-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9169-
dc.rightsDefault Licence-
dc.subjectfungicidesen
dc.subjectchlorothalonilen
dc.subject4-hydroxychlorothalonilen
dc.subjectair samplingen
dc.subjecthplcen
dc.subjectgas-chromatographyen
dc.subjectdegradation-productsen
dc.subjectagricultural soilen
dc.subjectchlorpyrifosen
dc.subjectpesticidesen
dc.subjecttransformationen
dc.subjectresiduesen
dc.subjectexposureen
dc.subjectwateren
dc.titleSimultaneous determination of chlorothalonil and its metabolite 4-hydroxychlorothalonil in greenhouse air: Dissipation process of chlorothalonilen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.chemosphere.2008.05.044-
heal.identifier.secondary<Go to ISI>://000259166200003-
heal.identifier.secondaryhttp://ac.els-cdn.com/S004565350800708X/1-s2.0-S004565350800708X-main.pdf?_tid=3f76a92083706876bb9eb1338be8ced6&acdnat=1333030727_3dd4d5f0e96ffe072c9048c1598e5247-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2008-
heal.abstractAn analytical method was developed and tested for the simultaneous determination of chlorothalonil and its main metabolite 4-hydroxychlorothalonil, in airborne samples. High performance liquid chromatography equipped with Ultra-violet detector was used to separate and quantify the analytes. Glass microfibre filters for the collection of the analytes' particles were tested. Solid sorbents, such as Tenax, Florisil, XAD-2 and silica gel, were studied to find out the most suitable material for the collection of the analytes in the gas phase. The results have shown that only chlorothalonil was trapped in the vapor phase with highest results obtained when silica gel was the sorbent of choice. Linearity was demonstrated in a wide concentration range 0.01-10.00 mg L-1. Recoveries from spiked glass microfibre filters and silica gel cartridges for chlorothalonil and 4-hydroxychlorothalonil were almost quantitative. The quantification limits were calculated to be 8.4 and 19.6 ng m(-3) in air for chlorothalonil and 4-hydroxychlorothalonil, respectively. The two analytes spiked on the GF/A filters and silica gel cartridges were proven to be stable for more than 15 days, at 4 degrees C and ambient temperature. The applicability of the present method was demonstrated by the analysis of the chlorothalonil and its metabolite in greenhouse air. (C) 2008 Elsevier Ltd. All rights reserved.en
heal.publisherElsevieren
heal.journalNameChemosphereen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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