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dc.contributor.authorSyrgiannis, Z.en
dc.contributor.authorKoutsianopoulos, F.en
dc.contributor.authorMuir, K. W.en
dc.contributor.authorElemes, Y.en
dc.date.accessioned2015-11-24T16:46:03Z-
dc.date.available2015-11-24T16:46:03Z-
dc.identifier.issn0040-4039-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9022-
dc.rightsDefault Licence-
dc.subjectene reactionsen
dc.subjecttriazolinedionesen
dc.subjectsolvent additionen
dc.subjectwater additionen
dc.subjectthermodynamic parametersen
dc.subjectx-rayen
dc.subjectene reactionen
dc.subjectn-phenyltriazolinedioneen
dc.subjectsinglet oxygenen
dc.subjectbenzyltriphenylphosphonium peroxymonosulfateen
dc.subjectthiolsen
dc.subjectdisulfidesen
dc.subjectoxidationen
dc.subjectsolventen
dc.subjectmechanismen
dc.subjectefficienten
dc.titleReaction of a triazolinedione with simple alkenes. Isolation and characterization of hydration productsen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.tetlet.2008.10.150-
heal.identifier.secondary<Go to ISI>://000263152800007-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0040403908020601/1-s2.0-S0040403908020601-main.pdf?_tid=f6cacca45afcda900d6ec87b257ff93f&acdnat=1333029130_9fb5da02b79327d3630a6785f23ebdb5-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2009-
heal.abstractThe reaction of N-phenyltriazolinedione with three simple alkyl-substituted alkenes in water/alcohol or water/acetone solution was found to give a mixture or the corresponding ene and water addition products. The new hydration products were characterized by spectroscopy, and in one case, also by X-ray diffraction analysis. Thermodynamic parameters were determined for the reactions involving 2-methylbut-2-ene, TriME, and 2,3-dimethylbut-2-ene, TetraMe, in accordance with an 'S(N)2-like', nucleophilic attack on a closed aziridinium imide (At) intermediate by water. (C) 2008 Elsevier Ltd. All rights reserved.en
heal.publisherElsevieren
heal.journalNameTetrahedron Letten
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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