alpha-Benzoin Oxime in Higher Oxidation State 3d Metal Cluster Chemistry: Structural and Magnetic Study of a New Mn-9(III) Complex (Journal article)

Koumousi, E. S./ Manos, M. J./ Lampropoulos, C./ Tasiopoulos, A. J./ Wernsdorfer, W./ Christou, G./ Stamatatos, T. C.

The initial employment of alpha-benzoin oxime (bzoxH(2)) in higher oxidation state 3d metal cluster chemistry has provided access to a new enneanuclear Mn-III complex with an unprecedented metal-core topology consisting of two triangular [Mn-3(mu(3)-O2-)(mu-ON)(3)](4+) fragments connected by a linear [Mn-3(mu-ON)(6)](3+) unit. The Mn-9(III) cluster is antiferromagnetically coupled and has an S=3 spin ground state.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: single-molecule magnets,high-spin molecules,manganese clusters,carboxylate,ligands
URI: https://olympias.lib.uoi.gr/jspui/handle/123456789/8965
ISSN: 0020-1669
Link: <Go to ISI>://000276073000003
http://pubs.acs.org/doi/pdfplus/10.1021/ic100178y
Publisher: American Chemical Society
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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