Photoreactive 3D microporous lanthanide MOFs: formation of a strained ladderane in a partial single crystal-to-single crystal manner (Journal article)

Michaelides, A./ Skoulika, S./ Siskos, M. G.

The assembly of Er(3+) and Y(3+) cations with trans,trans-muconic acid affords a photoreactive 3D microporous MOF that, upon UV irradiation, undergoes a cycloaddition reaction (SCSC up to 55%), with in situ formation of a strained ladderane.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: trans-cinnamic acid,solid-state,2+2 photodimerization,coordination polymer,structural transformations,organic-synthesis,reactivity,cycloaddition,derivatives,complexes
URI: https://olympias.lib.uoi.gr/jspui/handle/123456789/8841
ISSN: 1359-7345
Link: <Go to ISI>://000291613400034
http://pubs.rsc.org/en/content/articlepdf/2011/cc/c0cc05547f
Publisher: Royal Society of Chemistry
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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