Palladium(II) complexes of 4-formylantipyrine N(3)-substituted thiosemicarbazones: first example of X-ray crystal structure and description of bonding properties (Journal article)

Yadav, P. N./ Demertzis, M. A./ Kovala-Demertzi, D./ Skoulika, S./ West, D. X.

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dc.contributor.authorYadav, P. N.en
dc.contributor.authorDemertzis, M. A.en
dc.contributor.authorKovala-Demertzi, D.en
dc.contributor.authorSkoulika, S.en
dc.contributor.authorWest, D. X.en
dc.date.accessioned2015-11-24T16:43:57Z-
dc.date.available2015-11-24T16:43:57Z-
dc.identifier.issn0020-1693-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8757-
dc.rightsDefault Licence-
dc.subjectantipyrineen
dc.subjectthiosemicarbazoneen
dc.subjectpalladiumen
dc.subjectcrystal structureen
dc.subjectspectral studyen
dc.subjectelectrochemistryen
dc.subjectpyridine n-oxidesen
dc.subjectcopper(ii) complexesen
dc.subjectheterocyclic thiosemicarbazonesen
dc.subjectspectral propertiesen
dc.subjectn(4)-substituted thiosemicarbazonesen
dc.subjectzinc(ii) complexesen
dc.subjectantitumor-activityen
dc.subjectmetal-complexesen
dc.subjectplatinum(ii) complexesen
dc.subject2-acetyl pyridineen
dc.titlePalladium(II) complexes of 4-formylantipyrine N(3)-substituted thiosemicarbazones: first example of X-ray crystal structure and description of bonding propertiesen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1016/S0020-1693(03)00087-2-
heal.identifier.secondary<Go to ISI>://000183673100005-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0020169303000872/1-s2.0-S0020169303000872-main.pdf?_tid=22936bf04666732d0c14c03bf843b9ea&acdnat=1333028996_85f38918507ae0db3c79b23edc2b672d-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2003-
heal.abstractReaction of 4-formylantipyrine with thiosemicarbazide, N(3)-methylthiosemicarbazide and N(3)-ethylthiosemicarbazide produced the expected thiosemicarbazones, 1, 2 and 3. The three thiosemicarbazones were then reacted with K2PdCl4 to produce [Pd(NS)(2)] complexes, 4, 5, and 6, respectively, with coordination by the imine nitrogen and thiolate sulfur of the anionic thiosemicarbazone moiety. The thiosemicarbazones and their palladium complexes have been characterized by spectral IR, UV-Vis and H-1, C-13 NMR and electrochemical techniques. The crystal structure of 6 has been obtained and found to be highly symmetrical with a trans arrangement of the two bidentate ligands. (K) (C) 2003 Elsevier Science B.V. All rights reserved.en
heal.journalNameInorganica Chimica Actaen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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