Model investigations for vanadium-protein interactions: first vanadium(III) complexes with dipeptides and their oxovanadium(IV) analogues (Journal article)

Tasiopoulos, A. J./ Deligiannakis, Y. G./ Woollins, J. D./ Slawin, A. M. Z./ Kabanos, T. A.

Reaction of the dipeptides H(2)Gly-Tyr and H(2)Gly-Phe with VCl3 and 1,10-phenanthroline affords the compounds [V(Gly-Tyr)(phen)]Cl . 3MeOH 1 and [V(Gly-Phe)(phen)]Cl . 3MeOH 2; aerial oxidation of the complexes 1 and 2 gives their oxovanadium(Iv) analogues [VO(Gly-Tyr)(phen)] 3 and [VO(Gly-Phe(phen)] 4, respectively; the X-ray crystal structure of 3 is reported.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: crystal-structure
ISSN: 1359-7345
Link: <Go to ISI>://000072481300021
Publisher: Royal Society of Chemistry
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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