Mercuration of acetone in the acetone-mercury(II) perchlorate-2-(2'pyridyl)quinoxaline(L) system (Journal article)

Garoufis, A./ Perlepes, S. P./ Froystein, N. A./ Sletten, J./ Hadjiliadis, N.

The 1:1 reaction of HS(ClO4)(2) . 3H(2)O with 2-(2'-pyridyl) quinoxaline(L) in acetone leads to isolation of [Hg(CH2COCH3)(ClO4)L](2); the X-ray crystal structure determination together with H-1- and C-13-NMR spectra reveal the presence of the coordinated 2-oxopropyl anion. L coordinates in a bidentate, highly asymmetric mode.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: 2-(2'-pyridyl)quinoxaline,complexes
URI: https://olympias.lib.uoi.gr/jspui/handle/123456789/8426
ISSN: 0277-5387
Link: <Go to ISI>://A1996TM13600040
http://ac.els-cdn.com/0277538795002543/1-s2.0-0277538795002543-main.pdf?_tid=b976b325746d3651604669bb7aa056a9&acdnat=1333029226_53807376614c0923b769b82ec6f9da0c
Publisher: Elsevier
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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