Kinetic-potentiometric assay of formaldehyde in pharmaceutical and industrial samples, monitored by copper solid ion selective electrode, after its reaction with the copper(II)-bis-(ethylenediamine) complex (Journal article)

Stergiou, D. V./ Karkabounas, S. C./ Veltsistas, P. G./ Evmiridis, N. P./ Vlessidis, A. G.


A kinetic-potentiometric method is described for the quantitative assay of formaldehyde ( HCHO) in pharmaceutical and industrial preparations. It is based on the reaction of HCHO with ( ethylenediamine)-Cu( II)sulfate [Cu(CH2NH2)(2)(H2O)(2)] center dot SO4. The changes in potential, resulting from the release of the Cu( II) cations, are monitored with a Cu( II)-ion selective electrode. The calibration curve for the HCHO is linear in the concentration range 50 - 250 mg L-1, with a limit of detection of 8.5 mg L-1. The method shows very good reproducibility with an RSD of 2.6% for successive injections (n = 5) of 150 mg L-1 HCHO primary solution, while it is interference free. The method was successfully tested in various industrial and pharmaceutical preparations.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: formaldehyde determination,kinetic determination,solid ion selective electrodes,amperometric detection,hydrogen-peroxide,air,chromatography,oxidation,biosensor,health,film
URI: http://olympias.lib.uoi.gr/jspui/handle/123456789/8321
ISSN: 0026-3672
Link: <Go to ISI>://000245888000003
http://download.springer.com/static/pdf/765/art%253A10.1007%252Fs00604-006-0676-9.pdf?auth66=1381994699_602ec5033030a0161748ab4a5a58f1e4&ext=.pdf
Publisher: Springer Verlag (Germany)
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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