Kinetic and Mechanistic Study of the Copper(Ii)-Oxamate Complexation, Monitored by the Cu-Ii Solid-State Ion-Selective Electrode (Journal article)

Karayannis, M. I./ Veltsistas, P. G./ Merkoci, A. X.


The complexation process of copper(II) with oxamates was followed by the use of a copper solid state ion selective electrode. The shape of the recorded potential vs. time was interpreted on the basis of the known kinetic expressions for a two step reaction, monitoring the consumption of the reagent. The potential changes of the electrode are attributed to a decrease in the copper concentration. The curves are of an exponential form with two distinct parts, the first due to the intermediate activated complex, which is produced very rapidly, and the second is due to the slow formation of the soluble chelate. The effects of various parameters are studied in relation to the retardation of the first step. The reaction rate constant k, the equilibrium constant K-* for the fist step, the stability constant K, the activation energy E(a), the change in enthalpy, and the product (pZ) of the frequency and steric factors were determined. On the basis of the above data, a mechanistic scheme for this complexation reaction is proposed.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: oxamic acid,copper(ii) oxamate chelate complexes,kinetic study of copper complexation,copper ion selective electrode,oxamic acid,mu-oxamido,oxamato,oxalato,bridges
URI: http://olympias.lib.uoi.gr/jspui/handle/123456789/8309
ISSN: 1040-0397
Link: <Go to ISI>://A1995QU51800002
http://onlinelibrary.wiley.com/store/10.1002/elan.1140070203/asset/1140070203_ftp.pdf?v=1&t=h1gl240x&s=8391c18974b3fb997078fe74a2d233034fa242c5
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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