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dc.contributor.authorTsogas, G. Z.en
dc.contributor.authorGiokas, D. L.en
dc.contributor.authorVlessidis, A. G.en
dc.contributor.authorEvmridis, N. P.en
dc.date.accessioned2015-11-24T16:38:44Z-
dc.date.available2015-11-24T16:38:44Z-
dc.identifier.issn0584-8547-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8077-
dc.rightsDefault Licence-
dc.subjectchromiumen
dc.subjectspeciationen
dc.subjectvesicular liquid coacervate extractionen
dc.subjectflame atomic absorption spectrometryen
dc.subjectnatural watersen
dc.subjectcloud point preconcentrationen
dc.subjectanionic surfactantsen
dc.subjectinjection-analysisen
dc.subjectorganic-compoundsen
dc.subjectphase-separationen
dc.subjectionic surfactanten
dc.subjectvesicle phasesen
dc.subjectadsorptionen
dc.subjectsamplesen
dc.subjectcoagelen
dc.titleA single-reagent method for the speciation of chromium in natural waters by flame atomic absorption spectrometry based on vesicular liquid coacervate extractionen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.sab.2004.04.008-
heal.identifier.secondary<Go to ISI>://000223388400005-
heal.identifier.secondaryhttp://ac.els-cdn.com/S058485470400117X/1-s2.0-S058485470400117X-main.pdf?_tid=b89d2b36-356a-11e3-a246-00000aacb35e&acdnat=1381822003_b33d88ac717458038048e7aede729eee-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2004-
heal.abstractThe concept of liquid coacervate extraction (LCE) is deployed to accomplish metal speciation after appropriate derivatization of the target metallic species. The method involves the partitioning of the hydrophobic metal chelates, produced from the reaction of Cr with APDC, in the vesicular aggregates formed from an anionic surfactant with alkaline earth metals and a cosurfactant, which are separated from the bulk aqueous phase. Under the established experimental conditions, the method offers high reproducibility., very low detection limits and recoveries in the range of 95 - 104%. Moreover, the method affords high tolerance for EDTA, which is used as a masking agent in order to avoid interferences from co-extracted metals. Validation of the outlined method was performed by analysing a certified reference material (BCR 544) yielding recoveries higher than 94% for both Cr oxidation states. (C) 2004 Elsevier B.V. All rights reserved.en
heal.publisherElsevieren
heal.journalNameSpectrochimica Acta Part B-Atomic Spectroscopyen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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