Microemulsions as a tool for the regioselective lipase-catalysed esterification of aliphatic diols (Journal article)

Macris, J. B./ Stamatis, H./ Kolisis, F. N.

The efficiency of Humicola lanuginosa and Candida cylindracea lipases to catalyse the regioselective esterification of butane-1,3-diol with oleic acid has been demonstrated in water-in-oil microemulsion systems stabilized with sodium (bis-2-ethylhexyl) sulphosuccinate as a surfactant in isooctane. Mono- and diesters were selectively synthesized with high reaction rates. The product distribution depends on the positional specificity of the lipases. Water-in-oil microemulsions appear to be an effective and fast system for the regioselective enzymatic esterification of diols.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιών
Keywords: Chemistry and Materials Science
URI: https://olympias.lib.uoi.gr/jspui/handle/123456789/7457
ISSN: 0175-7598
Link: http://dx.doi.org/10.1007/s002530050854
Publisher: Springer Berlin / Heidelberg
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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