Mpi Spectroscopy in the Region of the 3p Rydberg State of Some Cycloketones (Journal article)

Kosmidis, C./ Boulakis, G./ Bolovinos, A./ Tsekeris, P./ Brint, P.

The two-photon resonance three photon ionization spectra of cyclopentanone, cyclohexanone and cycloheptanone in the region of the 3p Rydberg state have been recorded, analysed and compared with the one-photon absorption spectra. A new 3p origin is identified for cyclopentanone. The absence from the MPI spectra of a sharp spectral feature that is observed in the absorption spectra is discussed. Photochemical generation of acetaldehyde is observed at high laser intensities and possible mechanisms for this are considered.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιών
Keywords: acetone
URI: https://olympias.lib.uoi.gr/jspui/handle/123456789/17605
ISSN: 0022-2860
Link: <Go to ISI>://A1992HM94800016
http://ac.els-cdn.com/002228609280058P/1-s2.0-002228609280058P-main.pdf?_tid=51f741fa-ada2-11e2-b6a4-00000aacb361&acdnat=1366892524_ca1db2f08d9babe5215949d010b54175
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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