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DC Field | Value | Language |
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dc.contributor.author | Misichronis, K. | en |
dc.contributor.author | Rangou, S. | en |
dc.contributor.author | Avgeropoulos, A. | en |
dc.date.accessioned | 2015-11-24T17:39:09Z | - |
dc.date.available | 2015-11-24T17:39:09Z | - |
dc.identifier.issn | 1023-666X | - |
dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/14598 | - |
dc.rights | Default Licence | - |
dc.subject | block copolymers | en |
dc.subject | molecular characterization | en |
dc.subject | morphology | en |
dc.subject | poly(p-trimethylsilyl styrene) | en |
dc.subject | poly(1,3-cyclohexadiene) | en |
dc.subject | living anionic-polymerization | en |
dc.subject | 1,3-cyclohexadiene polymers | en |
dc.subject | n-butyllithium/n,n,n',n'-tetramethylethylenediamine system | en |
dc.subject | star | en |
dc.subject | butadiene | en |
dc.subject | isoprene | en |
dc.subject | behavior | en |
dc.title | Synthesis and molecular and morphological characterization of poly(p-trimethylsilyl styrene) and diblock copolymers with poly(1,3-cyclohexadiene) | en |
heal.type | journalArticle | - |
heal.type.en | Journal article | en |
heal.type.el | Άρθρο Περιοδικού | el |
heal.identifier.primary | Doi 10.1080/10236660801924149 | - |
heal.identifier.secondary | <Go to ISI>://000255064400005 | - |
heal.identifier.secondary | http://www.tandfonline.com/doi/pdf/10.1080/10236660801924149 | - |
heal.language | en | - |
heal.access | campus | - |
heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικών | el |
heal.publicationDate | 2008 | - |
heal.abstract | We report the synthesis of a silylated monomer, specifically p-trimethylsilyl styrene, its homopolymerization, and its block copolymerization with 1,3-cyclohexadiene. Controlled Grignard reactions were adopted for the preparation of the monomer. Anionic polymerization high-vacuum techniques were employed for all polymerization procedures. The kinetics of poly(P-trimethylsilyl styrene) homopolymers were also studied. Molecular characterization for all intermediate and final products was accomplished via size exclusion chromatography, membrane osmometry, and proton nuclear magnetic resonance spectroscopy. Finally, the self-assembly of the block copolymers was studied with transmission electron microscopy, where well-ordered microstructures were observed (alternating lamellae and hexagonally closed packed cylinders). | en |
heal.publisher | Taylor & Francis | en |
heal.journalName | International Journal of Polymer Analysis and Characterization | en |
heal.journalType | peer reviewed | - |
heal.fullTextAvailability | TRUE | - |
Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά) |
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File | Description | Size | Format | |
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Misichronis-2008-Synthesis and molecu.pdf | 468.92 kB | Adobe PDF | View/Open Request a copy |
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