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dc.contributor.authorMisichronis, K.en
dc.contributor.authorRangou, S.en
dc.contributor.authorAvgeropoulos, A.en
dc.date.accessioned2015-11-24T17:39:09Z-
dc.date.available2015-11-24T17:39:09Z-
dc.identifier.issn1023-666X-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14598-
dc.rightsDefault Licence-
dc.subjectblock copolymersen
dc.subjectmolecular characterizationen
dc.subjectmorphologyen
dc.subjectpoly(p-trimethylsilyl styrene)en
dc.subjectpoly(1,3-cyclohexadiene)en
dc.subjectliving anionic-polymerizationen
dc.subject1,3-cyclohexadiene polymersen
dc.subjectn-butyllithium/n,n,n',n'-tetramethylethylenediamine systemen
dc.subjectstaren
dc.subjectbutadieneen
dc.subjectisopreneen
dc.subjectbehavioren
dc.titleSynthesis and molecular and morphological characterization of poly(p-trimethylsilyl styrene) and diblock copolymers with poly(1,3-cyclohexadiene)en
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1080/10236660801924149-
heal.identifier.secondary<Go to ISI>://000255064400005-
heal.identifier.secondaryhttp://www.tandfonline.com/doi/pdf/10.1080/10236660801924149-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.publicationDate2008-
heal.abstractWe report the synthesis of a silylated monomer, specifically p-trimethylsilyl styrene, its homopolymerization, and its block copolymerization with 1,3-cyclohexadiene. Controlled Grignard reactions were adopted for the preparation of the monomer. Anionic polymerization high-vacuum techniques were employed for all polymerization procedures. The kinetics of poly(P-trimethylsilyl styrene) homopolymers were also studied. Molecular characterization for all intermediate and final products was accomplished via size exclusion chromatography, membrane osmometry, and proton nuclear magnetic resonance spectroscopy. Finally, the self-assembly of the block copolymers was studied with transmission electron microscopy, where well-ordered microstructures were observed (alternating lamellae and hexagonally closed packed cylinders).en
heal.publisherTaylor & Francisen
heal.journalNameInternational Journal of Polymer Analysis and Characterizationen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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