2 Ternary Ni-Ii Complexes - Bisglycinato-(1,10-Phenanthroline)Nickel(Ii) Trihydrate and Bisglycinato(2,2'-Bipyridine)Nickel(Ii) Trihydrate (Journal article)

Skoulika, S./ Michaelides, A./ Aubry, A.

The two title compounds, [Ni(C2H4NO2)(2)(C12H8N2).]-3H(2)O and [Ni(C2H4NO2)(2)(C10H8N2)].3H(2)O, are isostructural. Their structures consist of discrete complex molecules, together with water molecules of crystallization. All ligands are bidentate and the coordination polyhedron is a distorted octahedron. Distinct segregation of hydrophilic and hydrophobic regions appears along the c axis. In the hydrophilic region a three-dimensional network of hydrogen bonds is formed involving principally the water molecules. Aromatic interactions exist in the hydrophobic region.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: structural-properties,coordination behavior,acid
URI: http://olympias.lib.uoi.gr/jspui/handle/123456789/10578
ISSN: 0108-2701
Link: <Go to ISI>://A1995RB59500024
Publisher: Munksgaard Int Publ Ltd.
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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